Oxidative Carbonylation of 2-Propyn-1-ol and 2-Methyl-3-butyn-2-ol in an Oscillatory Mode
نویسندگان
چکیده
منابع مشابه
2-Methyl-1,1,3,3-tetraphenylpropan-2-ol
The title compound, C(28)H(26)O, was synthesized by condensation of diphenyl-methyl-lithium and ethyl acetate. In one diphenyl-methyl group, the two benzene rings are rotated by 65.0 (3)° with respect to each other, while in the other diphenyl-methyl group, the dihedral angle between the two benzene rings is 84.1 (3)°.
متن کامل2-Aminopyridin-3-ol
The molecule of the title pyridine derivative, C(5)H(6)N(2)O, shows approximate C(s) symmetry. Intra-cyclic angles cover the range 118.34 (10)-123.11 (10)°. In the crystal, O-H⋯N, N-H⋯O and N-H⋯N hydrogen bonds connect the mol-ecules into double layers perpendicular to the a axis. The shortest centroid-centroid distance between two π-systems is 3.8887 (7) Å.
متن کاملKinetics of the solvent-free hydrogenation of 2-methyl-3-butyn-2-ol over a structured Pd-based catalyst
The solvent-free selective hydrogenation of 2-methyl-3-butyn-2-ol (MBY) to 2-methyl-3-buten-2-ol (MBE) was studied over a Pd/ZnO structured catalyst and compared to its behavior in water-assisted conditions. The catalytic behavior was correlated with the surface properties of the catalysts which were characterized by X-ray diffraction and X-ray photoelectron spectroscopy. The catalyst showed hi...
متن کامل3-Anilino-1-(isopropylamino)propan-2-ol
The title compound, C(12)H(20)N(2)O, was obtained by the reaction of N-(oxiran-2-ylmeth-yl)aniline and propan-2-amine. In the crystal, mol-ecules are linked by O-H⋯N and N-H⋯O hydrogen bonds into chains parallel to the b axis.
متن کامل1-(Isopropylamino)-3-phenoxypropan-2-ol
In the crystal structure of the title amino alcohol derivitive, C(12)H(19)NO(2), mol-ecules are linked by N-H⋯O hydrogen bonds. The mol-ecular structure exhibits an intra-molecular O-H⋯N hydrogen bond.
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ژورنال
عنوان ژورنال: Organic Chemistry International
سال: 2012
ISSN: 2090-200X,2090-2018
DOI: 10.1155/2012/819190